(Nano-) Particle Synthesis and Processing

 

The Laboratory for Multifunctional Materials has broad expertise in the wet-chemical synthesis of functional materials ranging from metal oxide and noble metal nanoparticles to lithium metal phosphates and bulk copper. In particular, we have pioneered the nonaqueous sol-gel synthesis of metal oxide nanoparticles, giving access to a wide range of compositions, sizes, shapes and thus properties that include magnetic, ferroelectric, dielectric, conductive or photocatalytically active nanoparticles. Nonaqueous sol–gel routes are based on the reaction of molecular precursors like metal halides, acetates, acetylacetonates, or alkoxides with organic solvents at temperatures between 50–250 °C (Figure 1a). Figure 1b displays a selection of transmission electron microscopy overview images of metal oxide nanoparticles and metal oxide-based organic-inorganic nanohybrids.

 

Enlarged view: synthesis_overview
Figure 1. (a) Schematic of the nonaqueous sol-gel synthesis approach to metal oxide nanoparticles using different precursor-solvent combinations. (b) Transmission electron microscopy overview images of selected metal oxide nanoparticles with some of their properties and digital photographs of nanoparticle dispersions of doped metal oxide nanoparticles and of a bulk tungsten oxide-based hybrid.

We are also familiar with the further processing of nanoparticles into thin films and porous structures such as aerogels, as well as the embedding of nanoparticles into polymers to produce composite materials. Understanding and controlling the surface chemistry of nanoparticles is critical for these processing steps to be successful. We have the appropriate methods for surface characterization as well as the expertise to prepare colloidal dispersions.

 

 

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